oral taxon 108, Campylobacter jejuni, uncultured Eubacterium sp., Tannerella, and Porphyromonas were identified. Oral microbiome dysbiosis was found in patients suffering from PVL. To the best of our knowledge, this is the first study investigating the oral microbiome alterations in PVL and, due to the limited number of participants, additional studies are needed. Oral microbiota-based biomarkers may be helpful in predicting the risks for the development of PVL.Oral microbiome dysbiosis was found in patients suffering from PVL. To the best of our knowledge, this is the first study investigating the oral microbiome alterations in PVL and, due to the limited number of participants, additional studies are needed. Oral microbiota-based biomarkers may be helpful in predicting the risks for the development of PVL.Tetracycline antibiotics as the emerging pollutants had been drawn abroad increasing concerns. An agricultural waste, the lignocellulosic hazelnut shell, was used as the carbon source to prepare the nanocomposites of zero-valent iron@biochar by pyrolytic reduction method at 1123 K for 2 h in N2 atmosphere. The adsorptive removal of tetracycline, oxytetracycline and chlortetracycline by the zero-valent iron@biochar from aqueous solution was investigated by batch method. The optimal experimental conditions were found to be at pH 6-7 with a contact time of 40 min. The adsorbed amounts of oxytetracycline, chlortetracycline and tetracycline at 298 K were 52.7, 42.5 and 39.1 mg g-1, respectively. Adsorption process of three antibiotics by the nanocomposite pursued Langmuir and pseudo-second-order equations. Thermodynamic parameters illustrated that the adsorption was spontaneous and endothermic intrinsically. The high removal efficiencies up to 95% of the zero-valent iron@biochar for oxytetracycline and chlortetracycline from the culture wastewaters had opened the potential applications for the removal of the antibiotics.In this work, the novel hollow mesoporous coagulant was prepared by chitosan-polydopamine coating and permanganate loading into silica nanoparticles for investigating the simultaneous enrichment and degradation of diclofenac sodium (DCFS) combined with ultraviolet irradiation. The enrichment kinetic of DCFS was explained well with pseudo-second-order model, indicating the exist of hydrogen bonding. Based on the correlation coefficients, the enriched isotherms were fitted by models which accorded with the BET > Freundlich > Langmuir sequence. The result showed that, in addition to the coagulant and DCFS, there were aromatic stackings among DCFS molecules. Due to both effects of which, the DCFS enrichment could be realized significantly in the range of pH 4.0-9.0. It was degraded at the copresence of ultraviolet and permanganate released from coagulant in acidic aqueous medium. The release mechanism was simulated through Korsmayer-Peppas model, implying case-II transport and Fickian diffusion. Additionally, Mn (V) and •OH radicals were vital in the DCFS degradation process. The coagulant could be reloaded at least ten times and that from each cycle was used directly for DCFS removal for six times without rinse process, which provided a potential application in environmental remediation.In a column set-up, Fe modified biochar produced from date palm leaves was used to remove As (1 mg L-1) from a laboratory-prepared wastewater. The wastewater treatment process was monitored in real-time by spectral induced polarization (SIP), over a wide range of frequencies (0.01-1000 Hz). Both 5 and 10% biochar-amended columns achieved As removal exceeding 98%. The SIP parameters appear to be sensitive on As removal processes, with the recorded trend following the conventional geochemical monitoring, while offering higher temporal resolution.Trifluralin is a widely used dinitroaniline herbicide in cotton fields of China but is highly persistent in the environment and can act as a biotoxin and cause genotoxicity to terrestrial organisms, including humans. In this study, the concentrations and distribution of trifluralin residues in 139 soil samples from the major cotton-producing areas of China were investigated. The trifluralin concentrations ranged from ND (not detected) to 66.39 μg/kg dry weight (dw), with a geometric mean of 4.13 μg/kg dw. The detection frequency of trifluralin in Hebei (75%) was higher than that in Xinjiang (66%) and Shandong (40%), but the mean trifluralin concentration was highest in Xinjiang (5.98 μg/kg dw), followed by Hebei (5.06 μg/kg dw) and Shandong (3.19 μg/kg dw). No trifluralin residues were detected in cotton soil in Anhui, Jiangxi and Hunan. The residual amount of trifluralin in soil was significantly correlated with the soil organic matter content. The risk quotient method was used to evaluate the ecological risks associated with trifluralin. Results indicated that trifluralin in all the samples had a low risk to earthworms, but trifluralin in same cotton soils showed high risks to wheat, barley and lucerne. CX-5461 manufacturer Overall, our work is helpful to understand the residual situation of trifluralin in Chinese cotton soil, to assess the environmental risk of trifluralin, and to control the use and safety of trifluralin in cotton field cultivation.A method is described here for the concentration and determination of geosmin and 2-methylisoborneol (2-MIB) from the gaseous phase, with translation to field collection and quantification from soil disturbances in situ. The method is based on the use of solid-phase microextraction (SPME) fibers for adsorption of volatile chemicals from the vapor phase, followed by desorption into a gas chromatograph-mass spectrometer (GC-MS) for analysis. The use of a SPME fiber allows simple introduction to the GC-MS without further sample preparation. Several fiber sorbent types were studied and the 50/30 μm DVB/CAR/PDMS was the best performer to maximize the detected peak areas of both analytes combined. Factors such as extraction temperature and time along with desorption temperature and time were explored with respect to analyte recovery. An extraction temperature of 30 °C for 10 min, with a desorption temperature of 230 °C for 4 min was best for the simultaneous analysis of both geosmin and 2-MIB without complete loss of either one.