Overall, co-doping with high-valent cations led to improved afterglow duration."Zero-strain" insertion materials are essential for high-performance Li-ion batteries, but the experimental determination of changes in their local structures remains challenging. In this study, we successfully visualized the reaction scheme of a perfect zero-strain material, (Li0.75Zn0.25)[Li0.417Ti1.583]O4 with a spinel framework, using operando X-ray diffraction (XRD) and X-ray absorption spectroscopy (XAS). The operando XRD/XAS technique, which provided a series of XRD, Ti K-edge XAS, and Zn K-edge XAS data, can be employed owing to a recently developed tapered undulator and monochromator system. Although previous ex situ XRD measurements indicated the immutable cubic lattice parameter (ac) during the discharge process, these studies unveiled drastic structural variations occurring on the atomic scale between the charge and discharge reactions, such as differences in the ac, bond distances, and occupancies of the Zn2+ ions. This dynamic information obtained under operating conditions could be useful not only for understanding the zero-strain reaction scheme but also for designing advanced zero-strain insertion materials with enhanced energy density.Neutron diffraction measurements on 6Li/7Li isotopically substituted 10 and 33 mol % *LiTFSA (lithium bis(trifluoromethylsulfonyl)amide)-AN-d3 (acetonitrile-d3) and 10 and 33 mol % *LiTFSA-DMF-d7(N,N-dimethylformamide-d7) solutions have been carried out in order to obtain structural insights on the first solvation shell of Li+ in highly concentrated organic solutions. Structural parameters concerning the local structure around Li+ have been determined from the least squares fitting analysis of the first-order difference function derived from the difference between carefully normalized scattering cross sections observed for 6Li-enriched and natural abundance solutions. In 10 mol % LiTFSA-AN-d3 solution, 3.25 ± 0.04 AN molecules are coordinated to Li+ with a intermolecular Li+···N(AN) distance of 2.051 ± 0.007 Å. It has been revealed that 1.67 ± 0.07 AN molecules and 2.00 ± 0.01 TFSA- are involved in the first solvation shell of Li+ in the 33 mol % LiTFSA-AN solution. The nearest neighbor Li+···NAN and Li+···OTFSA- distances are obtained to be r(Li+···N) = 2.09 ± 0.01 Å and r(Li+···O) = 1.88 ± 0.01 Å, respectively. The first solvation shell of Li+ in the 10 mol % LiTFSA-DMF-d7 solutions contains 3.4 ± 0.1 DMF molecules with an intermolecular Li+···ODMF distance of 1.95 ± 0.02 Å. In highly concentrated 33 mol % LiTFSA-DMF-d7 solutions, there are 1.3 ± 0.2 DMF molecules and 3.2 ± 0.2 TFSA- in the first solvation shell of Li+ with intermolecular distances of r(Li+···ODMF) = 1.90 ± 0.02 Å and r(Li+···OTFSA-) = 2.01 ± 0.01 Å, respectively. The Li+···TFSA- contact ion pair stably exists in highly concentrated 33 mol % LiTFSA-AN and -DMF solutions.A high filler content is often needed in polymer composite-based thermoelectric (TE) films to improve their performance. Nevertheless, this often leads to poor processability and poor mechanical performance. Herein, a biomimetic approach is adopted to facilitate the filler content up to 90.5 wt % in free-standing and flexible n-type PVDF/Ag2Se TE films, where PVDF dendricolloids are a solution mixed with Ag2Se nanowires (NWs), followed by filtration. These soft dendric nanoparticles within PVDF dendricolloids have high adhesivity and strong network-building ability, which allows the formation of "grapevine-grape"-like networks with soft dendritic particles and inorganic TE fillers as "grapevine" and "manicure finger grapes", respectively. The maximum power factor of 189.02 μW m-1 K-2 is achieved for a PVDF/Ag2Se mass ratio of 19.5 at 300 K. https://www.selleckchem.com/products/INCB18424.html Meanwhile, excellent flexibility with only 15.8% decrease in electrical conductivity after 1000 bending cycles was observed. These properties at such a high filler content are attributed to the long-range grapevine-like network of soft PVDF dendritic particles and entanglement between numerous Ag2Se NWs. This work carves a path to fabricate high-performance free-standing flexible n-type TE composite films as well as other functional polymer composites requiring high inorganic filler loading.Photocatalytic CO2 reduction has been considered as a promising approach to solve energy and environmental problems. Nevertheless, developing inexpensive photocatalysts with high efficiency and selectivity remains a big challenge. In this study, two Co-based complexes [Co2(L1)Cl2] (1-Co) and [Co(L2)Cl] (2-Co) were synthesized by treating two DPA-based (DPA dipicolylamine) ligands with Co2+, respectively. Under visible-light irradiation, the performance of 1-Co as a homogeneous photocatalyst for CO2 reduction in aqueous media has been explored by using [Ru(phen)3]2+ as a photosensitizer, and triethylolamine (TEOA) as a sacrificial reductant. 1-Co shows high photocatalytic activity for CO2-to-CO conversion, corresponding to the high TONCO of 2600 and TOFCO of 260 h-1 (TONCO = turnover number for CO; TOFCO = turnover frequency for CO). High selectivity of 97% for CO formation is also achieved. The control experiments catalyzed by 2-Co demonstrated that two Co(II) centers in 1-Co may operate independently and activate one CO2 molecule each. Furthermore, the proposed mechanism of 1-Co for photocatalytic CO2 reduction has been investigated via electrochemical analysis, a series of quenching experiments, and density functional theory calculations.Four binuclear tridentate copper(I) complexes were synthesized based on the trans effect of the hybrid ligands. The catalytic performance and behavior of the prepared copper(I) complexes were evaluated in the carboxylative cyclization of propargylic amines with CO2. The combined use of copper(I) complexes and 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD) provided a catalytic system for the synthesis of a wide range of oxazolidinones from various propargylic amines and CO2 under mild reaction conditions (room temperature-40 °C and 1 bar CO2). The key factor for the success of the protocol is the use of copper complexes possessing the quality of hemilabile properties between N-heterocyclic carbenes and nitrogen donors. NMR measurements, density functional theory (DFT) calculations, and previous reports for the coordination behavior of the nickel complexes support the existence of the trans effect between N-heterocyclic carbenes and nitrogen donors.